HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → 1,6-Dichloro-2-aminonaphthalene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Potassium Hydroxide | HCID 14797 | — |
| Reactant | N-(1,6-dichloro-2-naphthyl)carbamic acid ethyl ester | HCID 68803921 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | 1,6-Dichloro-2-aminonaphthalene | HCID 18451479 | — |
Reaction Steps
A mixture of N-(1,6-dichloro-2-naphthyl)carbamic acid ethyl ester (750 mg, 2.64 mmol) and KOH (1.78 mg, 31.7 mmol) in ethanol (20 mL) is heated to reflux temperature under a N2 atmosphere for 12 hours. After cooling to room temperature, water (10 mL) is added. The resulting precipitation is removed by filtration to give 1,6-dichloro-2-aminonaphthalene as a solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07202364B2 |
| Source dataset | uspto-grants-2007_04 |
| ORD ID | ord-fda9c74ec485406bab2b56cdd6fbde73 |
| Source note | uspto-grants-2007_04 |