Sodium Hydroxide → 3,5-dimercaptobenzyl alcohol

HRID 1271667Notes

Reaction equation

CN(C)C([S:5][C:6]1[CH:7]=[C:8]([CH:11]=[C:12]([S:14]C(=O)N(C)C)[CH:13]=1)[CH2:9][OH:10])=O.[OH-].[Na+]>>[SH:5][C:6]1[CH:7]=[C:8]([CH:11]=[C:12]([SH:14])[CH:13]=1)[CH2:9][OH:10]

Participants

Reactant 2

HCID 14798Sodium Hydroxide

HCID 12138352HCID 12138352, compound

Product 1

HCID 121383533,5-dimercaptobenzyl alcohol

Procedure

3,5-Bis(dimethylcarbamoylthio)benzyl alcohol was treated with sodium hydroxide according to the ordinary method to give 3,5-dimercaptobenzyl alcohol. This alcohol was then brominated in a manner similar to that in EXAMPLE 17, giving 3,5-dimercaptobenzyl bromide, followed by the reaction with urea according to the ordinary method giving 3,5-dimercaptobenzyl mercaptan.

Sources & evidence

ORD record: ord-c11bc8d5739947179276680376e7fc50
Source dataset: uspto-grants-2007_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07205428B2

Reaction notes

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