Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Carbon Dioxide | HCID 280 | — |
| Reactant | Tetraaminopyrimidine sulfate | HCID 79358 | — |
| Reactant | Sodium Bicarbonate | HCID 516892 | — |
| Reactant | Bis(3-hydroxyphenyl)ethane-1,2-dione | HCID 13158606 | — |
| Solvent | Water | HCID 962 | — |
| Product | TG-100115 | HCID 10427712 | — |
Reaction Steps
4.76 g (20.0 mmol) of 2,4,5,6-tetraaminopyrimidine sulfate was added in small portions to a solution of 3.36 g (40.0 mmol) sodium bicarbonate in 100 mL of water with vigorous stirring. A brisk evolution of CO2 gas was observed. The resulting suspension was heated to 80° C. and 4.84 g (20.0 mmol) of 3,3′-dihydroxybenzil was added to the mixture. The reaction mixture was refluxed for 3 hours, at which point a bright-yellow precipitate was formed in abundance.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US07208493B2 |
|---|
| Source dataset | uspto-grants-2007_04 |
|---|
| ORD ID | ord-522b09ee20b4459ea396a9b1905b0c9f |
|---|
| Source note | uspto-grants-2007_04 |
|---|
