HRID127364

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CCCCCCCCc1ccc(Nc2ccc(CCCCCCCC)cc2)cc1

HCID7569

4,4'-Dioctyldiphenylamine

C28H43N

HCID15519329

未命名化合物

PRODUCTS

生成物

结构：CCCCCCCCc1ccc(N(c2ccc(CCCCCCCC)cc2)C2(c3ccc(N(C)C)cc3C)OC(=O)c3ccccc32)cc1

HCID20287195

未命名化合物

收率 46.8%

PROCEDURE

实验过程

Following a procedure similar to that described in Example 1 but employing 5.7 g of 2-[4-(dimethylamino)-2-methylbenzoyl]benzoic acid and 8.0 g of 4,4'-dioctyldiphenylamine there was obtained 6.2 g of 3-[4-(dimethylamino)-2-methylphenyl]-3-[bis(4-octylphenyl)amino]phthalide, m.p. 172°-174° C. A toluene solution of the product contacted with acidic clay or phenolic resin developed a red-colored image.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-b905ff3f6eee4eaaa4c97d9fc71d5607
来源数据集: uspto-grants-1981_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04255577
来源说明: uspto-grants-1981_03

反应 SMILES

[CH3:1][N:2]([CH3:21])[C:3]1[CH:19]=[CH:18][C:6]([C:7]([C:9]2[CH:17]=[CH:16][CH:15]=[CH:14][C:10]=2[C:11]([OH:13])=O)=[O:8])=[C:5]([CH3:20])[CH:4]=1.[CH3:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][C:30]1[CH:35]=[CH:34][C:33]([NH:36][C:37]2[CH:42]=[CH:41][C:40]([CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH3:50])=[CH:39][CH:38]=2)=[CH:32][CH:31]=1>>[CH3:21][N:2]([CH3:1])[C:3]1[CH:19]=[CH:18][C:6]([C:7]2([N:36]([C:37]3[CH:38]=[CH:39][C:40]([CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH3:50])=[CH:41][CH:42]=3)[C:33]3[CH:32]=[CH:31][C:30]([CH2:29][CH2:28][CH2:27][CH2:26][CH2:25][CH2:24][CH2:23][CH3:22])=[CH:35][CH:34]=3)[C:9]3[C:10](=[CH:14][CH:15]=[CH:16][CH:17]=3)[C:11](=[O:13])[O:8]2)=[C:5]([CH3:20])[CH:4]=1