Aluminum(III) Chloride → HCID 20284769, compound

Participants

Reaction Steps

A suspension of the product of the above (2) (1.40 g) in ether (40 ml) is added dropwise to a suspension of lithium aluminium hydride (467 mg) and aluminium chloride (1.63 g) in ether. The mixture is stirred at room temperature for 2.5 hours and extracted with ether-ethyl acetate after addition of an aqueous solution of sodium hydroxide. The extract is condensed. The residue is crystallized from ethyl acetate-methanol to give the title compound as white crystals (1.13 g) melting at 136°-138° C. Yield: 79%.

Provenance & Evidence