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HRID1275496

反应详情

EQUATION

反应方程式

HRID 1275496 的结构方程式

REACTANTS

反应物

2
结构：COc1ccc(C(=O)Cl)cc1C(C)(C)C
HCID13633555

3-(1,1-Dimethylethyl)-4-methoxybenzoyl chloride

C12H15ClO2

结构：COC(=O)c1ccc(C#C[Si](C)(C)C)cc1O
HCID22641103

未命名化合物

PRODUCTS

生成物

1
结构：COc1ccc(C(=O)C#Cc2ccc(C(=O)O)c(O)c2)cc1C(C)(C)C
HCID22619423

未命名化合物

收率 85.1%

PROCEDURE

实验过程

Following the basic procedure of Example 1(b), by reacting 4.2 g (0.02 mol) of 3-tert-butyl-4-methoxybenzoyl chloride with 5 g (0.02 mol) of methyl 2-hydroxy-4-trimethylsilylethynylbenzoate, 6 g (81%) of the expected compound were obtained, after purification by chromatography on a silica column eluted with dichloromethane, in the form of a brown oil.