2,7-Dibromo-9-fluorenone → 2,7-Dibromo-9-phenyl-9H-fluoren-9-ol

HRID 1275738Notes

Reaction equation

HRID 1275738 reaction equation
[C:1]1([Mg]Cl)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Br:9][C:10]1[CH:22]=[CH:21][C:20]2[C:19]3[C:14](=[CH:15][C:16]([Br:23])=[CH:17][CH:18]=3)[C:13](=[O:24])[C:12]=2[CH:11]=1>>[Br:9][C:10]1[CH:22]=[CH:21][C:20]2[C:19]3[C:14](=[CH:15][C:16]([Br:23])=[CH:17][CH:18]=3)[C:13]([C:1]3[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=3)([OH:24])[C:12]=2[CH:11]=1

Participants

3

Reactant 2

HCID 2599222,7-Dibromo-9-fluorenoneHCID 178478979HCID 178478979, compound

Product 1

HCID 221175462,7-Dibromo-9-phenyl-9H-fluoren-9-ol

Procedure

from phenylmagnesium chloride and 2,7-dibromo-9-fluorenone;

Sources & evidence

ORD record
ord-2e1b9d1f2f264ca0828566f3b248e77d
Source dataset
uspto-grants-2000_12
Patent number
US06162824

Reaction notes

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