3-Amino-5,5-dimethyl-2-cyclohexen-1-one → HCID 22117866, compound

HRID 1275845Notes

Reaction equation

HRID 1275845 reaction equation
[NH2:1][C:2]1[CH2:7][C:6]([CH3:9])([CH3:8])[CH2:5][C:4](=[O:10])[CH:3]=1.[Cl:11][C:12]1[CH:13]=[C:14]([CH:24]=[C:25]([Cl:27])[CH:26]=1)[O:15][C:16]1[CH:17]=[C:18]([CH:21]=[CH:22][CH:23]=1)[CH:19]=O>>[Cl:11][C:12]1[CH:13]=[C:14]([CH:24]=[C:25]([Cl:27])[CH:26]=1)[O:15][C:16]1[CH:17]=[C:18]([CH:19]2[C:3]3[C:4](=[O:10])[CH2:5][C:6]([CH3:9])([CH3:8])[CH2:7][C:2]=3[NH:1][C:2]3[CH2:7][C:6]([CH3:9])([CH3:8])[CH2:5][C:4](=[O:10])[C:3]2=3)[CH:21]=[CH:22][CH:23]=1

Participants

3

Reactant 2

HCID 1366803-Amino-5,5-dimethyl-2-cyclohexen-1-oneHCID 6880503-(3,5-Dichlorophenoxy)benzaldehyde

Product 1

HCID 22117866HCID 22117866, compound

Procedure

3-Amino-5,5-dimethyl-2-cyclohexen-1-one was reacted with 3-(3,5-dichlorophenoxy)-benzaldehyde in an analogous manner to that described in Example 1 to give 9-[3-(3,5-dichlorophenoxy)-phenyl]-3,4,6,7,9,10-hexahydro-3,3,6,6-tetramethyl-1,8(2H,5H)-acridinedione. Crystallization from dimethylformamide/water gave a yellow crystalline solid of melting point 254-255° C.

Sources & evidence

ORD record
ord-6eb661e03bd740f7b8ece9feb70f9f26
Source dataset
uspto-grants-2000_12
Patent number
US06162918

Reaction notes

Loading…