HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Chlorotrimethylsilane → Silane, trimethyl[[2-methyl-1-(1-methylethyl)-1-propenyl]oxy]-
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Chlorotrimethylsilane | HCID 6397 | — |
| Edukt | 2,4-Dimethyl-3-pentanone | HCID 11271 | — |
| Produkt | Silane, trimethyl[[2-methyl-1-(1-methylethyl)-1-propenyl]oxy]- | HCID 11095327 | — |
Reaktionsschritte
Reaction between 2,4-dimethyl-3-pentanone (1.2.4.3), trimethylsilyl chloride, and base gave 2,4-dimethyl-3-trimethysilyloxy-2-pentene (1.2.4.4) which was reacted with 1-fluoropyridinium triflate (1.2.4.5) to form 2,4-dimethyl-2-fluoro-3-pentanone (1.2.4.6). This product was reacted with (CH3)3S(O)+ l- to form the title compound (1.2.4.2). ##STR31##
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US06165996 |
| Quelldatensatz | uspto-grants-2000_12 |
| ORD ID | ord-6d6a2c462e494bd0b1e71567dfbfe056 |
| Quellennotiz | uspto-grants-2000_12 |