1-Butanol → 1-Butene, 3-butoxy-

HRID 1276844Notes

Reaction equation

HRID 1276844 reaction equation
[CH2:1]([OH:5])[CH2:2][CH2:3][CH3:4].[CH2:6]=[CH:7][CH:8]=[CH2:9]>>[CH2:1]([O:5][CH:8]([CH3:9])[CH:7]=[CH2:6])[CH2:2][CH2:3][CH3:4].[CH2:1]([O:5][CH2:6][CH:7]=[CH:8][CH3:9])[CH2:2][CH2:3][CH3:4]

Participants

4

Reactant 2

HCID 2631-ButanolHCID 78451,3-Butadiene

Product 2

HCID 5437051-Butene, 3-butoxy-HCID 5439041-Butoxybut-2-ene

Procedure

0.90 mol of n-butanol and 0.88 mol of 1,3-butadiene were reacted in a manner similar to Example 8b) in the presence of 5 g of the zeolite in the H+ form, prepared according to Example 8a). At a conversion of 40.0%, 3-butoxybut-1-ene was formed with a selectivity of 42.5% and 1-butoxybut-2-ene with a selectivity of 16.5%.

Workup

  1. customprepared

Sources & evidence

ORD record
ord-b909ab406e1a4450ade8cb6dc3e03805
Source dataset
uspto-grants-2000_12
Patent number
US06166265

Reaction notes

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