(1,1'-Biphenyl)-2-carboxaldehyde → HCID 23453836, compound

HRID 1277371Notes

Reaction equation

HRID 1277371 reaction equation
[CH:1]([C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)=[O:2].Cl.[CH3:16][N:17]([CH3:23])[CH2:18][CH2:19][CH2:20][Mg][Cl:22]>>[Cl-:22].[CH3:16][NH+:17]([CH2:18][CH2:19][CH2:20][CH:1]([OH:2])[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[CH3:23]

Participants

3

Reactant 2

HCID 121052(1,1'-Biphenyl)-2-carboxaldehydeHCID 178483495HCID 178483495, compound

Product 1

HCID 23453836HCID 23453836, compound

Procedure

By a similar procedure, 2-formyl-1,1'-biphenyl was reacted with 3-dimethylaminopropyl magnesium chloride hydrochloride to provide N,N-dimethyl-4-hydroxy-4-(1,1'-biphenyl-2-yl)butylaminium chloride. M.P. 161°-164° C.

Sources & evidence

ORD record
ord-3cf984b834684d59a325f7ebe0f03a06
Source dataset
uspto-grants-1981_07
Patent number
US04277471

Reaction notes

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