HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → BOC-Tyr-(D)-Met(O)-Gly-OH
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | BOC-Tyr-(D)-Met(O)-Gly-MePhe-NHNH-CO-CH3 | HCID 12919692 | — |
| Product | BOC-Tyr-(D)-Met(O)-Gly-OH | HCID 12919648 | — |
| Product | H-Tyr-(D)-Met(O)-Gly-MePhe-NHNH-CO-CH3 | HCID 12919694 | — |
Reaction Steps
Using 0.35 g of BOC-Tyr-(D)-Met(O)-Gly-MePhe-NHNH-CO-CH3, in a similarmanner to (IV) of Example 36 is obtained 0.19 g of the desired product, [α]D22 0° (c=0.25, MeOH), Rf2 =0.16, amino acid analysis: Gly 1.00, Met 1.00, Tyr 1.20.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04277394 |
| Source dataset | uspto-grants-1981_07 |
| ORD ID | ord-fc0a07ee532c4de3a11d89be3b047254 |
| Source note | uspto-grants-1981_07 |