HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrochloric Acid → 2,2-Dimethyl-11-isopropyl-11-amino-undecanal oxime
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | Hydroxyamine hydrochloride | HCID 443297 | — |
| Reactant | 3,3-Dimethyl-12-isopropyl-1-aza-cyclododecene | HCID 20436097 | — |
| Solvent | Water | HCID 962 | — |
| Product | 2,2-Dimethyl-11-isopropyl-11-amino-undecanal oxime | HCID 73678915 | 94% |
Reaction Steps
The procedure described in Example (1b) is repeated, except that 118.7 g (0.5 mol) of 3,3-dimethyl-12-isopropyl-1-aza-cyclododecene, 35 g (0.5 mol) of hydroxylamine hydrochloride, 55 g of 37% hydrochloric acid, 200 mlof water and 50 g (1.25 mols) of solid sodium hydroxide are used. Distillation yields 127 g (0.47 mol) of 2,2-dimethyl-11-isopropyl-11-amino-undecanal oxime; yield 94% of theory; boiling point 145° C./4 Pa; nD20 =1.4761.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04277621 |
| Source dataset | uspto-grants-1981_07 |
| ORD ID | ord-f95f2e1f1dea4cd7a1802adeb6168933 |
| Source note | uspto-grants-1981_07 |