HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbon Dioxide → CID 112285
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbon Dioxide | HCID 280 | — |
| Reactant | Malonic Acid | HCID 867 | — |
| Reactant | Piperidine | HCID 8082 | — |
| Reactant | Benzaldehyde, 2-methoxy-5-nitro- | HCID 90685 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Pyridine | HCID 1049 | — |
| Product | CID 112285 | HCID 112285 | — |
Reaction Steps
Piperidine (1 ml) was added to a mixture of 2-methoxy-5-nitrobenzaldehyde (24 g) and malonic acid (30 g) in pyridine (about 60 ml). The mixture was warmed on a steam bath for 3 hours (slow evolution of carbon dioxide) and then poured into water (500 ml) when a yellow solid precipitated. The solid was removed by filtration and crystallized from ethanol (1 liter). The weight of the product was 20 grams.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04278748 |
| Source dataset | uspto-grants-1981_07 |
| ORD ID | ord-bc51dc92e4b84cdc8632a37b56a90ab8 |
| Source note | uspto-grants-1981_07 |