HCID 12769229, compound → HCID 21163102, compound

HRID 1278252Notes

Reaction equation

HRID 1278252 reaction equation
[N:1]([CH:4]1[C:11](=[O:12])[N:10]2[CH:5]1[CH2:6][CH2:7]OC2(C)C)=[N+:2]=[N-:3].O=C1N2C(CCOC2(C)C)C1.[Si:26](N1C(C=C)CC1=O)([C:29]([CH3:32])([CH3:31])[CH3:30])([CH3:28])[CH3:27]>>[Si:26]([N:10]1[CH:5]([CH:6]=[CH2:7])[CH:4]([N:1]=[N+:2]=[N-:3])[C:11]1=[O:12])([C:29]([CH3:32])([CH3:31])[CH3:30])([CH3:28])[CH3:27]

Participants

4

Reactant 3

HCID 12769229HCID 12769229, compoundHCID 12769232HCID 12769232, compoundHCID 140681691-(t-Butyldimethylsilyl)-4-vinyl-2-azetidinone

Product 1

HCID 21163102HCID 21163102, compound

Procedure

Following the procedure described for the preparation of 7-azido-8-oxo-2,2-dimethyl-3-oxa-1-azabicyclo[4.2.0]-octane from 8-oxo-2,2-dimethyl-3-oxa-1-azabicyclo[4.2.0]-octane (Example 5, Step A) and using 1-(t-butyldimethylsilyl)-4-vinyl-2-azetidinone there is obtained 1-(t-butyldimethylsilyl)-3-azido-4-vinyl-2-azetidinone. ##STR46##

Sources & evidence

ORD record
ord-d14c3807fca04b1cb50e2bd8557785b1
Source dataset
uspto-grants-1981_07
Patent number
US04281002

Reaction notes

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