HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl fluorosulfate → 5-Cyano-3,4-dichloro-2-methyl isothiazolium fluorosulfonate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl fluorosulfate | HCID 9870 | — |
| Reactant | Dichloro-1,2-thiazole-5-carbonitrile | HCID 19738264 | — |
| Product | 5-Cyano-3,4-dichloro-2-methyl isothiazolium fluorosulfonate | HCID 12889029 | 77% |
Reaction Steps
5-Cyano-3,4-dichloroisothiazole (3.6 g, 0.02 mol) and 4 ml of methyl fluorosulfonate were heated at 80°-100° for 11/2 hrs under a nitrogen atmosphere. The resulting solid was washed with ether and benzene to yield 4.5 g (77%) of 5-cyano-3,4-dichloro-2-methyl isothiazolium fluorosulfonate, mp 163-174 (d). Spectral data (NMR and IR) were consistent with the assigned structure.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04281136 |
| Source dataset | uspto-grants-1981_07 |
| ORD ID | ord-b6b1bb4ceeb8491d9bcc3e0939115734 |
| Source note | uspto-grants-1981_07 |