HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diethyl Ether → 2-Octyl-3,4,5-trichloroisothiazolium trifluoromethane sulfonate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diethyl Ether | HCID 3283 | — |
| Reactant | Octyl triflate | HCID 10869071 | — |
| Reactant | Trichloroisothiazole | HCID 12333154 | — |
| Solvent | Acetone cardice | HCID 18522661 | — |
| Product | 2-Octyl-3,4,5-trichloroisothiazolium trifluoromethane sulfonate | HCID 14535709 | 31% |
Reaction Steps
Trichloroisothiazole (6.6 g, 0.035 mol) and n-octyl trifluoromethane sulfonate (7.5 g, 0.0286 mol) were heated at 110° for 2 hrs. After cooling, 150 ml of ether was added and solution cooled in dry ice/acetone bath. The ether was decanted and the brown oil dried to yield 4.0 g (31%) of product. Spectral data (NMR & IR) were consistent with the assigned structure.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04281136 |
| Source dataset | uspto-grants-1981_07 |
| ORD ID | ord-4c09c3b50a0e407b8579e2971fe24420 |
| Source note | uspto-grants-1981_07 |