HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanesulfonic Acid → Methane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanesulfonic Acid | HCID 6395 | — |
| Reactant | N,N-Diethyl-m-phenetidine | HCID 74625 | — |
| Reactant | Sodium p-toluenesulfinate | HCID 2723791 | — |
| Product | Methane | HCID 297 | — |
| Product | [Bis(4-dimethylaminophenyl)(4-methylphenylsulfonyl)]methane | HCID 20184810 | — |
Reaction Steps
Ten and three tenths grams of 86.4 percent sodium p-toluenesulfinate, 10.7 g of 90.7 percent N,N-diethyl-3-ethoxyaniline and 12 g of 4-(N-ethyl-N-benzyl)-aminobenzaldehyde were interacted in the presence of 18.2 g of 95 percent methanesulfonic acid to obtain a methane of Formula XV wherein R=4--CH3 ; R5 =C2H5O; R6 =N(C2H5)2 ; Q=4--[(C2H5)(C6H5CH2)NC6H4 ], an oil. A significant infrared maximum appeared at 1145 (SO2 ; s) cm-1. The product developed a violet colored image.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04257954 |
| Source dataset | uspto-grants-1981_03 |
| ORD ID | ord-1d4c91b81707442fa2df58279e46075d |
| Source note | uspto-grants-1981_03 |