m-Chloroperbenzoic acid → HCID 23470801, compound

Participants

Reaction Steps

A solution of 1.22 g. (0.005 mole) of 3-(p-acetamidophenylthio)propyl chloride in 25 ml. of methylene chloride is cooled in an ice bath while 0.88 g. (0.005 mole) of m-chloro-perbenzoic acid is added in portions. After keeping at room temperature overnight the reaction mixture is washed with excess 0.5 N sodium hydroxide, dried, and concentrated to a light brown oil. By triturating with ether, 1.06 g. of 3-(p-acetamidophenylsulfinyl)propyl chloride is obtained. Anal. Calcd for C11H14ClNO2S: C, 50.86; H, 5.43; N, 5.39; Cl, 13.65. Found: C, 50.53; H, 5.59; N, 5.23; Cl, 13.67.

Provenance & Evidence