Methylhydrazine → HCID 20536309, compound

HRID 128066Notes

Reaction equation

HRID 128066 reaction equation
[IH:1].CS[C:4]1[NH:5][CH2:6][CH2:7][N:8]=1.[CH3:9][NH:10][NH2:11]>C(O)C>[IH:1].[CH3:9][N:10]([C:4]1[NH:5][CH2:6][CH2:7][N:8]=1)[NH2:11]

Participants

4

Reactant 2

HCID 6061MethylhydrazineHCID 122212281H-Imidazole, 4,5-dihydro-2-(methylthio)-, hydriodide (1:1)

Product 1

HCID 20536309HCID 20536309, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Conditions

Temperature
-10 °C

Procedure

A solution of 48.8 g. of 2-methylthio-2-imidazoline hydroiodide and 10.0 g. of methylhydrazine in 200 ml. of ethanol is heated at reflux for several hours, clarified and then cooled at -10° C. The precipitate is collected, washed with diethyl ether and dried, giving 2-(1-methylhydrazino)-imidazoline hydroiodide.

Workup

  1. temperatureat reflux for several hours
  2. customThe precipitate is collected
  3. washwashed with diethyl ether
  4. customdried

Sources & evidence

ORD record
ord-f5e4f11d925d44648f9a743e92142310
Source dataset
uspto-grants-1981_03
Patent number
US04258181

Reaction notes

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