HuagongsheHuagongshe Chemistry Print Report · For research reference only
2,3-Dimethylfuran → 2-Naphthalen-2-ylmethyl-4,5-dimethylfuran
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2,3-Dimethylfuran | HCID 34337 | — |
| Reactant | 2-Bromomethylnaphthalene | HCID 70320 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | 2-Naphthalen-2-ylmethyl-4,5-dimethylfuran | HCID 23445611 | — |
Reaction Steps
The title compound was prepared according to the procedure in Example 5, step 1 using 2,3-dimethylfuran, 2-(bromomethyl)naphthalene and 1.6M n-BuLi/hexanes in THF. 1H NMR (DMSO-d6) δ 1.89 (s, 3H), 2.15 (s, 3H), 4.08 (s, 2H), 5.95 (s, 1H), 7.40 (d, 1H), 7.45-7.57 (m, 2H), 7.77 (s, 1H), 7.83-7.91 (m, 3H).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06451845B1 |
| Source dataset | uspto-grants-2002_09 |
| ORD ID | ord-6c911743020c4603a6b235d84545fed8 |
| Source note | uspto-grants-2002_09 |