참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | p-Toluenesulfonic acid | HCID 6101 | — |
| 반응물 | Acetophenone | HCID 7410 | — |
| 반응물 | 2-Hydroxy-3-nitrobenzenecarbohydrazide | HCID 11367606 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | 3-Nitrosalicylic (1-phenylethylidene)hydrazide | HCID 72780903 | 93.6% |
반응 단계
A solution of 1.0 g (5 mmol) of 3-nitrosalicylohydrazide in 50 ml of anhydrous ethanol were treated with 0.6 g (5 mmol) of acetophenone and with a catalytic amount of p-toluenesulfonic acid. After the mixture had been stirred for 14 hours at approximately 20 to 25° C. and the solvent had been distilled off, 1.4 g of the title compound (90% of theory) were obtained as colorless crystals of m.p.: 163-168° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US06455515B2 |
|---|
| 출처 데이터셋 | uspto-grants-2002_09 |
|---|
| ORD ID | ord-721e0148b62d4141af3a9cd7c704abed |
|---|
| 출처 메모 | uspto-grants-2002_09 |
|---|
