1-Chloro-2,4-Dinitrobenzene → HCID 86737625, compound

HRID 128177Notes

Reaction equation

HRID 128177 reaction equation
[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1Cl)([O-:3])=[O:2].[CH2:14](O)[CH2:15][CH2:16][OH:17].[OH-:19].[Na+]>>[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1[O:19][CH:16]([OH:17])[CH2:15][CH3:14])([O-:3])=[O:2]

Participants

4

Reactant 3

HCID 61-Chloro-2,4-DinitrobenzeneHCID 104421,3-Propanediol2×HCID 14798Sodium Hydroxide

Product 1

HCID 86737625HCID 86737625, compound

Procedure

To a mixture of 0.2 mol (40.5 g) of 2,4-dinitro chlorobenzene and of 1.12 mol (81 cm3) of 1,3-propanediol, heated to 90° C. is added in 30 minutes 1.1 mol (81 cm3) of 1,3-propanediol in 20 cm3 of 10 N sodium hydroxide.

Sources & evidence

ORD record
ord-ca96291606a5486291387593ba92fb90
Source dataset
uspto-grants-1981_03
Patent number
US04259261

Reaction notes

Loading…