Diethyl Ether → Butylnorbornene

HRID 1282274Notes

Reaction equation

HRID 1282274 reaction equation
[CH3:1]COCC.[C:6]([C:10]1[CH:15]=[CH:14][CH:13]=[C:12]([C:16]([CH3:19])([CH3:18])C)N=1)([CH3:9])(C)C>C1(C)C=CC=CC=1.C([Pd]Cl)C=C>[CH2:15]([C:14]12[CH2:18][CH:16]([CH2:12][CH2:13]1)[CH:19]=[CH:1]2)[CH2:10][CH2:6][CH3:9]

Participants

5

Reactant 2

HCID 3283Diethyl EtherHCID 685102,6-Di-tert-butylpyridine

Product 1

HCID 19091267Butylnorbornene

Reagents, catalysts & solvents 2

HCID 178455862HCID 178455862, compoundCatalystHCID 1140TolueneSolvent4×

Procedure

A 50 weight percent solution of butylnorbornene (5.0 g, 0.033 mol) was prepared in toluene. Lithium tetrakis(pentafluorophenyl)borate·2.5 Et2O (0.0012 g, 0.0014 mmol) was combined with (allyl)palladiumchloride dimer (100 μl of a 1.4 mmol solution in toluene) and 2,6-di-t-butylpyridine (100 μl of a 2.9 mmol solution in toluene) in toluene and added to the monomer mixture. A polymeric puck formed within 5-10 min at room temperature.

Workup

  1. additionadded to the monomer mixture
  2. customA polymeric puck formed within 5-10 min at room temperature

Sources & evidence

ORD record
ord-b59f3598b6b14c97960b0aa8203d3145
Source dataset
uspto-grants-2002_09
Patent number
US06455650B1

Reaction notes

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