1-Iodohexane → HCID 86584052, compound

HRID 1282386Notes

Reaction equation

HRID 1282386 reaction equation
[C:1]([C:9]1[N:13]([CH3:14])[C:12]([CH2:15][C:16]([O:18]CC)=[O:17])=[CH:11][C:10]=1[CH3:21])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C(I)CCCCC>>[CH2:15]([C:12]1[N:13]([CH3:14])[C:9]([C:1](=[O:8])[C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=2)=[C:10]([CH3:21])[CH:11]=1)[CH3:16].[CH2:12]([CH2:15][C:16]([O-:18])=[O:17])[CH2:11][CH2:10][CH2:9][CH2:1][CH3:2]

Participants

3

Reactant 2

HCID 125271-IodohexaneHCID 15870188Ethyl (5-benzoyl-1,4-dimethyl-1H-pyrrol-2-yl)acetate

Product 1

HCID 86584052HCID 86584052, compound

Procedure

The alkylation procedure of Example 77A is performed upon ethyl 5-benzoyl-1,4-dimethylpyrrole-2-acetate (from Example 86), using an equivalent quantity of n-hexyl iodide instead of methyl iodide used in Example 77A to yield ethyl 5-benzoyl-1,4-dimethylpyrrole-2-(α-n-hexyl)-acetate.

Sources & evidence

ORD record
ord-1286f63721f242e69064fce305fb1521
Source dataset
uspto-grants-2002_09
Patent number
US06455703B2

Reaction notes

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