Methanol → Methyl 2-oxoimidazolidine-1-carboxylate

HRID 1282799Notes

Reaction equation

HRID 1282799 reaction equation
Cl[C:2]([N:4]1[CH2:8][CH2:7][NH:6][C:5]1=[O:9])=[O:3].[CH3:10][OH:11]>>[CH3:10][O:11][C:2]([N:4]1[CH2:8][CH2:7][NH:6][C:5]1=[O:9])=[O:3]

Participants

3

Reactant 2

HCID 887MethanolHCID 832412-Oxoimidazolidine-1-carbonyl chloride

Product 1

HCID 11788357Methyl 2-oxoimidazolidine-1-carboxylate

Procedure

14.9 parts by weight of N-chlorocarbonyl-imidazolid-2-one were introduced into 70 parts by volume of ice-cold methanol and the mixture was stirred for 1 hour at room temperature and subsequently for 1 hour at 40°-50° C. After the excess methanol had been stripped off, the residue was recrystallized from acetone.

Workup

  1. customthe residue was recrystallized from acetone

Sources & evidence

ORD record
ord-55cd6877eb2146229d06aec2ace6dc21
Source dataset
uspto-grants-1976_08
Patent number
US03972869

Reaction notes

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