HuagongsheHuagongshe Chemistry Print Report · For research reference only
Chlorotrimethylsilane → 3-(Methylsulphonyl)-2-oxoimidazolidine-1-carbonyl chloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Chlorotrimethylsilane | HCID 6397 | — |
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | 1,4-Dioxane | HCID 31275 | — |
| Reactant | 1-(Methylsulphonyl)imidazolidin-2-one | HCID 3016296 | — |
| Product | 3-(Methylsulphonyl)-2-oxoimidazolidine-1-carbonyl chloride | HCID 3016299 | — |
Reaction Steps
16.4 parts by weight of 1-methylsulphonyl-imidazolid- 2-one in dioxane were boiled for 3 days with 27 parts by weight of trimethylchlorosilane and 20 parts by weight of triethylamine. The triethylamine hydrochloride which precipitated was filtered off, 11 parts by weight of phosgene were added to the filtrate and the mixture was left to stand overnight at room temperature. It was then evaporated to dryness and the residue recrystallized from boiling acetone.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03972869 |
| Source dataset | uspto-grants-1976_08 |
| ORD ID | ord-964c28c6db62456baa8e588c347000e0 |
| Source note | uspto-grants-1976_08 |