HCID 23468725, compound → HCID 70579947, compound

HRID 128290Notes

Reaction equation

HRID 128290 reaction equation
[Cl:1][C:2]1[CH:3]=[CH:4][C:5]2[C:9]([S:10]([N:13]([CH2:15][C:16]([O:18][CH2:19]C)=[O:17])[CH3:14])(=[O:12])=[O:11])=[C:8]([C:21](OC)=[O:22])[S:7][C:6]=2[CH:25]=1>CO>[Cl:1][C:2]1[CH:3]=[CH:4][C:5]2[C:9]3[S:10](=[O:12])(=[O:11])[N:13]([CH3:14])[C:15]([C:16]([O:18][CH3:19])=[O:17])=[C:21]([OH:22])[C:8]=3[S:7][C:6]=2[CH:25]=1

Participants

3

Reactant 1

HCID 23468725HCID 23468725, compound

Product 1

HCID 70579947HCID 70579947, compoundYield 35%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

Prepared analogous to Example 1(e) from methyl 6-chloro-3-{[(ethoxycarbonyl-methyl)-methylamino]sulfonyl}-benzo[b]-thiophene-2-carboxylate by reaction with sodium methylene in anhydrous methanol with a yield of 35% of theory.

Sources & evidence

ORD record
ord-232e22bddc044364ba88a91e237aaf9a
Source dataset
uspto-grants-1981_03
Patent number
US04259336

Reaction notes

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