Hydrazine → HCID 21518773, compound

HRID 1282976Notes

Reaction equation

HRID 1282976 reaction equation
[C:1]([C:4]1[C:5]2[C:10]([C:11]3[CH:12]=[CH:13][CH:14]=[CH:15][C:16]=3[C:17]=1[N+:18]([O-])=O)=[CH:9][CH:8]=[CH:7][CH:6]=2)(=[O:3])[CH3:2].NN>[Ni]>[C:1]([C:4]1[C:5]2[C:10]([C:11]3[CH:12]=[CH:13][CH:14]=[CH:15][C:16]=3[C:17]=1[NH2:18])=[CH:9][CH:8]=[CH:7][CH:6]=2)(=[O:3])[CH3:2]

Participants

4

Reactant 2

HCID 9321HydrazineHCID 21518781HCID 21518781, compound

Product 1

HCID 21518773HCID 21518773, compound

Reagents, catalysts & solvents 1

HCID 935NickelCatalyst

Procedure

The pure 9-acetyl-10-nitrophenanthrene is reduced with hydrazine and Raney nickel to give 9-acetyl-10-aminophenanthrene. This is purified by recrystallization from toluene.

Sources & evidence

ORD record
ord-05543f7b4e314318aac07e6395db13ea
Source dataset
uspto-grants-1976_08
Patent number
US03973966

Reaction notes

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