HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → Methyl 4-methoxyphenylacetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | Water | HCID 962 | — |
| Reactant | Sodium Dithionite | HCID 24489 | — |
| Reactant | 4-Methyloxybenzyl chloride | HCID 69993 | — |
| Reactant | Sodium Methoxide | HCID 10942334 | — |
| Catalyst | Manganese | HCID 23930 | — |
| Product | Methyl 4-methoxyphenylacetate | HCID 90266 | — |
Reaction Steps
In the manner described in Example 1, 50 g of p-methoxybenzyl chloride was reacted with CO together with 115 g of a 24 wt-% solution of sodium methylate in methanol, 12 g CoCl2. 6 H2O , 6 g manganese and 1 g Na2S2O4. After distillation of the reaction mixture the following compounds could be identified by gas chromatography:p-methoxybenzyl chloride 10.00%p-methoxymethylbenzylether 69.50%-p-methoxyphenylaceticacid methyl ester 8.66%p-methoxyphenylaceticacid 5.54%
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03974202 |
| Source dataset | uspto-grants-1976_08 |
| ORD ID | ord-c69b7cf68e7f4423a3996962c4e62038 |
| Source note | uspto-grants-1976_08 |