Ammonia → Ammonia

Participants

Reaction Steps

To the stirred tank reactor is fed phosphoric acid, part of which has been used to recover ammonia losses from the granulator and drier described later. The combined phosphoric acid and partially ammoniated acid have an overall NH3 :H3PO4 molar ratio of 0.2:1 and a temperature of 75°C. Sulphuric acid at 40°C is also fed to this reactor. Off-gas ammonia (at 112°C, 0.5 kg/cm2 gauge and 9% NH3) from the pressure reaction vessel is bubbled through the acids in the stirred tank to give a solution of ammonium phosphate having an NH3 :H3PO4 molar ratio of 0.26:1, at its boiling point of 115°C and a water content of 35%. This solution is pumped at a pressure of 4 kg/cm2 gauge into the pressure reaction vessel into which is fed ammonia gas at 75°C obtained by vapourising liquid ammonia. The pressure reaction vessel is operated at 140°C and 0.85 kg/cm2 gauge to give a boiling solution of ammonium phosphate having an NH3 :H3PO4 molar ratio of 1.45:1 and containing 12% water. The off-gases from the pressure reaction vessel contain 6% NH3 in water vapour. These off-gases are passed through a heat exchanger to vapourise and heat the liquid ammonia feed to the pressure reaction vessel. As a result, the off-gases are cooled to 112°C and part of the water vapour is condensed out. The condensate is removed and the off-gases are recycled to the stirred tank reactor.

Provenance & Evidence