HCID 5365829, compound → HCID 23337994, compound

HRID 1283362Notes

Reaction equation

HRID 1283362 reaction equation
[CH3:1][C:2]12[O:10][C:3]1([C:11](=[O:15])/[CH:12]=[CH:13]/[CH3:14])[C:4]([CH3:9])([CH3:8])[CH2:5][CH2:6][CH2:7]2>O1CCOCC1>[CH3:1][C:2]1[C:3]([OH:10])([C:11](=[O:15])/[CH:12]=[CH:13]/[CH3:14])[C:4]([CH3:8])([CH3:9])[CH2:5][CH2:6][CH:7]=1

Participants

3

Reactant 1

HCID 5365829HCID 5365829, compound

Product 1

HCID 23337994HCID 23337994, compound

Reagents, catalysts & solvents 1

HCID 312751,4-DioxaneSolvent

Procedure

A mixture of the cis- and trans-isomers of 2,6,6-trimethyl-1-crotonoyl-1,2-epoxycyclohexane (10 g.) [cf. Example 32] and 2 g. of acid diatomaceous earth in 50 ml. of dioxan was heated under nitrogen at 100°-105°.

Sources & evidence

ORD record
ord-4b6743c560eb45539bfa7d0438c88fe8
Source dataset
uspto-grants-1976_08
Patent number
US03975310

Reaction notes

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