Chlorotrimethylsilane → HCID 13031822, compound

HRID 1283438Notes

Reaction equation

[NH:1]1[CH2:6][CH2:5][CH2:4][NH:3][C:2]1=[O:7].C[Si](C)(C)Cl.[S:13](Cl)([CH3:16])(=[O:15])=[O:14]>>[S:13]([N:1]1[CH2:6][CH2:5][CH2:4][NH:3][C:2]1=[O:7])([CH3:16])(=[O:15])=[O:14]

Participants

Reactant 3

HCID 6397Chlorotrimethylsilane

HCID 31297Methanesulfonyl chloride

HCID 746152(1H)-Pyrimidinone, tetrahydro-

Product 1

HCID 13031822HCID 13031822, compound

Procedure

This compound was produced as described in Example 35 C from 10 parts by weight of 1,3-diaza-cyclohexan-2-one, 49 parts by weight of trimethylchlorosilane and 30 parts by weight of mesylchloride. The reaction product was recrystallized from acetone at low temperature and thereafter from acetone/ethanol.

Workup

customThis compound was produced
customThe reaction product was recrystallized from acetone at low temperature

Sources & evidence

ORD record: ord-62428dc81e064502b44c003cd48e0481
Source dataset: uspto-grants-1976_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US03975375

Reaction notes

Loading…