Zincchloride → HCID 178487599, compound

HRID 1283489Notes

Reaction equation

HRID 1283489 reaction equation
[CH3:1][O:2][C:3]1[CH:4]=[C:5]2[C:10](=[CH:11][CH:12]=1)[CH:9]=[C:8]([Mg]Br)[CH:7]=[CH:6]2.[Cl-].[Zn+2:16].[Cl-]>C1C=CC=CC=1>[CH3:1][O:2][C:3]1[CH:4]=[C:5]2[C:10](=[CH:11][CH:12]=1)[CH:9]=[C:8]([Zn:16][C:8]1[CH:7]=[CH:6][C:5]3[C:10](=[CH:11][CH:12]=[C:3]([O:2][CH3:1])[CH:4]=3)[CH:9]=1)[CH:7]=[CH:6]2

Participants

4

Reactant 2

HCID 3007855ZincchlorideHCID 178487536HCID 178487536, compound

Product 1

HCID 178487599HCID 178487599, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

The resulting solution of 6-methoxy-2-naphthylmagnesium bromide in 50 ml. of benzene under nitrogen is added 3.14 g. of anhydrous zinc chloride. The temperature of the mixture is maintained at a temperature of from 25°-30°C for 1 hour, yielding a solution of di-(6-methoxy-2-naphthyl)zinc.

Workup

  1. temperatureThe temperature of the mixture is maintained at a temperature of from 25°-30°C for 1 hour

Sources & evidence

ORD record
ord-d41af099abdd4c85984617692f50deff
Source dataset
uspto-grants-1976_08
Patent number
US03975432

Reaction notes

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