Ethoxyethylamine → HCID 21453292, compound

HRID 1283687Notes

Reaction equation

HRID 1283687 reaction equation
[CH2:1]([O:3][CH2:4][CH2:5][NH2:6])[CH3:2].CN=[C:9]1[S:12][CH2:11][S:10]1.C(N=C1SCS1)(C)C.C(N=C1SCS1)(C)(C)C.C(N=C1SCS1)CCCCCCC>>[CH2:1]([O:3][CH2:4][CH2:5][N:6]=[C:9]1[S:12][CH2:11][S:10]1)[CH3:2]

Participants

6

Reactant 5

HCID 66970EthoxyethylamineHCID 21453285HCID 21453285, compoundHCID 21453308HCID 21453308, compoundHCID 21453319N-Octyl-1,3-dithietan-2-imineHCID 21819934HCID 21819934, compound

Product 1

HCID 21453292HCID 21453292, compound

Procedure

Following this procedure, but substituting the appropriate amine for 2-ethoxyethylamine, yields the compounds listed as follows:Example No. Compound m.p. °C.__________________________________________________________________________67 2-(Methylimino)-1,3-dithietane --68 2-(Isopropylimino)-1,3-dithietane --69 2-(tert-Butylimino)-1,3-dithietane oil70 2-(Heptylimino)-1,3-dithietane oil71 2-(Dodecylimino)-1,3-dithietane 40.5-4272 2-(Cyclohexylimino)-1,3-dithietane 78-8073 2-(Methylallylimino)-1,3-dithietane oil74 2-(Isobutylimino)-1,3-dithietane oil75 2-(1,4-Dimethylpentylimino)-1,3- oil dithietane76 2-(n-Octylimino)-1,3-dithietane oil77 2-(n-Hexylimino)-1,3-dithietane oil__________________________________________________________________________

Workup

  1. customyields the compounds

Sources & evidence

ORD record
ord-bdc7f5caa20949a9920df2d2366951a0
Source dataset
uspto-grants-1976_08
Patent number
US03975528

Reaction notes

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