HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzoic Acid → Isobutyl benzoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzoic Acid | HCID 243 | — |
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | Ethyl Acetate | HCID 8857 | — |
| Reactant | HCID 54067442 | HCID 54067442 | — |
| Solvent | Water | HCID 962 | — |
| Product | Isobutyl benzoate | HCID 61048 | 95.5% |
Reaction Steps
A mixture comprising benzoic acid (1.22 g), ethyl 2-isobutoxycarbonyloxyimino-2-cyanoacetate (2.42 g), triethylamine (1.4 ml) and ethyl acetate (20 ml) is stirred at room temperature for 1 hour and then admixed with water. The ethyl acetate layer is separated and treated as in Example A to give isobutyl benzoate (1.7 g) as an oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03976635 |
| Source dataset | uspto-grants-1976_08 |
| ORD ID | ord-3c2b7f78dc1a4669bd165f656cf504b5 |
| Source note | uspto-grants-1976_08 |