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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1283765Generated: October 31, 2026

Benzoic Acid → Isobutyl benzoate

https://huagongshe.com/reaction/1283765

Reaction equation

Participants

RoleNameHCIDCharge
ReactantBenzoic AcidHCID 243—
ReactantTriethylamineHCID 8471—
ReactantEthyl AcetateHCID 8857—
ReactantHCID 54067442HCID 54067442—
SolventWaterHCID 962—
ProductIsobutyl benzoateHCID 6104895.5%

Reaction Steps

A mixture comprising benzoic acid (1.22 g), ethyl 2-isobutoxycarbonyloxyimino-2-cyanoacetate (2.42 g), triethylamine (1.4 ml) and ethyl acetate (20 ml) is stirred at room temperature for 1 hour and then admixed with water. The ethyl acetate layer is separated and treated as in Example A to give isobutyl benzoate (1.7 g) as an oil.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS03976635
Source datasetuspto-grants-1976_08
ORD IDord-3c2b7f78dc1a4669bd165f656cf504b5
Source noteuspto-grants-1976_08