HCID 20335004, compound → HCID 20335168, compound

HRID 1284356Notes

Reaction equation

HRID 1284356 reaction equation
[OH:1][CH2:2][C:3]1[CH:4]=[C:5]2[C:10](=[CH:11][CH:12]=1)[CH:9]=[C:8]([CH:13]([CH3:17])[C:14]([OH:16])=[O:15])[CH:7]=[CH:6]2>[O-2].[O-2].[Mn+4].C(Cl)(Cl)Cl>[CH:2]([C:3]1[CH:4]=[C:5]2[C:10](=[CH:11][CH:12]=1)[CH:9]=[C:8]([CH:13]([CH3:17])[C:14]([OH:16])=[O:15])[CH:7]=[CH:6]2)=[O:1]

Participants

4

Reactant 1

HCID 20335004HCID 20335004, compound

Product 1

HCID 20335168HCID 20335168, compound

Reagents, catalysts & solvents 2

HCID 178418406HCID 178418406, compoundCatalystHCID 6212ChloroformSolvent

Procedure

A mixture of 23 g. of 6-hydroxymethyl-2-naphthyl-α-methylacetic acid, 230 g. of manganese dioxide, and 2 l. of chloroform are stirred for 12 hours; the mixture is filtered an evaporated to give 6-formyl-2-naphthyl-α-methylacetic acid.

Workup

  1. additionA mixture of 23 g
  2. filtrationthe mixture is filtered
  3. customan evaporated

Sources & evidence

ORD record
ord-fa7999d7a9e24f48a68d2b415346cc7c
Source dataset
uspto-grants-1976_08
Patent number
US03978116

Reaction notes

Loading…