m-Chloroperbenzoic acid → HCID 70468415, compound

Participants

Reaction Steps

To a stirring solution of 4-methoxy-6-[1-(phenylselenyl)ethyl]-2-pyrimidinamine (14.3 mmol) in 100 ml of CH2Cl2 cooled to -78° C. was added in one portion m-chloroperbenzoic acid (14.3 mmol). The solution was warmed to room temperature, diluted with ether and filtered. A white crystalline solid (0.17 g), m.p. 119°-122° C. was isolated. NMR (200 MHz, CDCl3) δ 3.87 (s, 3H); 5.9 (br s, 2H); 5.5 (d, d, 1H); 6.0 (s, 1H); 6.2-6.6 (m, 2H).

Provenance & Evidence