Solketal → 2,3-(dimethylmethylenedioxy)propyl P-ethyl-2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenylphosphinate

HRID 1284433Notes

Reaction equation

HRID 1284433 reaction equation
[CH2:1]([P:3](Cl)([C:5]1[CH:10]=[C:9]([O:11][C:12]2[CH:17]=[CH:16][C:15]([C:18]([F:21])([F:20])[F:19])=[CH:14][C:13]=2[Cl:22])[CH:8]=[CH:7][C:6]=1[N+:23]([O-:25])=[O:24])=[O:4])[CH3:2].[CH3:27][C:28]1([CH3:35])[O:34][CH2:33][CH:30]([CH2:31][OH:32])[O:29]1>>[CH2:1]([P:3]([C:5]1[CH:10]=[C:9]([O:11][C:12]2[CH:17]=[CH:16][C:15]([C:18]([F:20])([F:19])[F:21])=[CH:14][C:13]=2[Cl:22])[CH:8]=[CH:7][C:6]=1[N+:23]([O-:25])=[O:24])(=[O:4])[O:32][CH2:31][CH:30]1[O:29][C:28]([CH3:35])([CH3:27])[O:34][CH2:33]1)[CH3:2]

Participants

3

Reactant 2

HCID 7528SolketalHCID 13456450P-ethyl-2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenylphosphinic acid chloride

Product 1

HCID 135644422,3-(dimethylmethylenedioxy)propyl P-ethyl-2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenylphosphinate

Procedure

Following the procedure of Example 45, P-ethyl-2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenylphosphinic acid chloride and 2,3-(dimethylmethylenedioxy)-1-propanol are reacted together to yield 2,3-(dimethylmethylenedioxy)propyl P-ethyl-2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenylphosphinate, m/s 523 (M+). ##STR34##

Workup

  1. customare reacted together

Sources & evidence

ORD record
ord-561942b208674a0fa045d367c26c879a
Source dataset
uspto-grants-1986_01
Patent number
US04563310

Reaction notes

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