Dimethyl ethylphosphonite → methyl P-ethyl-2-nitro-5-(2-nitro-4-trifluoromethylanilino)-phenylphosphinate

HRID 1284437Notes

Reaction equation

[N+:1]([C:4]1[CH:22]=[C:21]([C:23]([F:26])([F:25])[F:24])[CH:20]=[CH:19][C:5]=1[NH:6][C:7]1[CH:12]=[CH:11][C:10]([N+:13]([O-:15])=[O:14])=[C:9]([N+]([O-])=O)[CH:8]=1)([O-:3])=[O:2].[CH2:27]([P:29]([O:32]C)[O:30][CH3:31])[CH3:28]>>[CH2:27]([P:29]([C:9]1[CH:8]=[C:7]([NH:6][C:5]2[CH:19]=[CH:20][C:21]([C:23]([F:24])([F:25])[F:26])=[CH:22][C:4]=2[N+:1]([O-:3])=[O:2])[CH:12]=[CH:11][C:10]=1[N+:13]([O-:15])=[O:14])(=[O:32])[O:30][CH3:31])[CH3:28]

Participants

Reactant 2

HCID 2784207Dimethyl ethylphosphonite

HCID 202515614-(2-Nitro-4-trifluoromethylanilino)-1,2-dinitrobenzene

Product 1

HCID 54100665methyl P-ethyl-2-nitro-5-(2-nitro-4-trifluoromethylanilino)-phenylphosphinate

Procedure

Following the procedure of Example 11, 4-(2-nitro-4-trifluoromethylanilino)-1,2-dinitrobenzene and dimethyl ethylphosphonite are reacted together to give methyl P-ethyl-2-nitro-5-(2-nitro-4-trifluoromethylanilino)-phenylphosphinate.

Workup

customare reacted together

Sources & evidence

ORD record: ord-c6ed9fc0a9fe40a5b1634b5abf2fff86
Source dataset: uspto-grants-1986_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04563310

Reaction notes

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