HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Acid → HCID 12676668, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | 4-Bromophenylhydrazine hydrochloride | HCID 12157 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | N-(dimethylaminomethylene)-p-nitrobenzamide | HCID 12550338 | — |
| Solvent | 1,4-Dioxane | HCID 31275 | — |
| Product | HCID 12676668 | HCID 12676668 | — |
Reaction Steps
To a solution of 12.1 g. of 4-bromophenylhydrazine hydrochloride in a mixture of 10.9 ml. of 5 N sodium hydroxide, 100 ml. of 30% aqueous acetic acid and 50 ml. of p-dioxane is added 10.0 g. of N-(dimethylaminomethylene)-p-nitrobenzamide. The procedure of Example 2 is followed, giving 12.7 g. of the desired product as tan crystals, mp. 142°-144° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04259504 |
| Source dataset | uspto-grants-1981_03 |
| ORD ID | ord-93d8d167564e44ea8fadd9cfc15330e7 |
| Source note | uspto-grants-1981_03 |