HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sulfuryl chloride → Ethyl 4-chloro-3-oxo-2-propargyloxyiminobutyrate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sulfuryl chloride | HCID 24648 | — |
| Reactant | Ethyl 2-propargyloxyimino-3-oxobutyrate | HCID 53965351 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | Ethyl 4-chloro-3-oxo-2-propargyloxyiminobutyrate | HCID 53939675 | 73.7% |
Reaction Steps
Ethyl 2-propargyloxyimino-3-oxobutyrate (syn isomer, 71.2 g.), acetic acid (81 ml.) and sulfuryl chloride (50.2 g.) were treated in a similar manner to that of Example F-(2) to give ethyl 4-chloro-3-oxo-2-propargyloxyiminobutyrate (syn isomer, 61.6 g.), oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04563522 |
| Source dataset | uspto-grants-1986_01 |
| ORD ID | ord-3fe3de8afee24efc958460ad1fcf8c46 |
| Source note | uspto-grants-1986_01 |