HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl Acrylate → Ethyl 3-(4-nitrophenyl)-2-propenoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl Acrylate | HCID 8821 | — |
| Reactant | 1-Bromo-4-nitrobenzene | HCID 11466 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Product | Ethyl 3-(4-nitrophenyl)-2-propenoate | HCID 95370 | 88% |
Reaction Steps
The procedure described in Example 26 is repeated, but using 5.05 g (25 mmols) of 4-bromonitrobenzene and 2.99 ml (27.5 mmols) of ethyl acrylate. After a reaction time of 3 hours at 130° C., 4.86 g (22.0 mmols) of ethyl 4-nitrocinnamate are obtained, corresponding to a yield of 88% of theory (conversion figure 8800; Pd content 0.01 mol %).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04564479 |
| Source dataset | uspto-grants-1986_01 |
| ORD ID | ord-12e9710d8fdc4b15a000d589b0f735ed |
| Source note | uspto-grants-1986_01 |