HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl Acrylate → Ethyl 3-phenylprop-2-enoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl Acrylate | HCID 8821 | — |
| Reactant | Iodobenzene | HCID 11575 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Product | Ethyl 3-phenylprop-2-enoate | HCID 7649 | 66.4% |
Reaction Steps
The procedure described in Example 9 is repeated, but using 2.79 ml (25 mmols) of iodobenzene and 2.98 ml (27.5 mmols) of ethyl acrylate. After a reaction time of 4.5 hours at 130° C., 2.92 g (16.6 mmols) of ethyl cinnamate are obtained, corresponding to a yield of 66% of theory (conversion figure 6600; Pd content 0.01 mol %).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04564479 |
| Source dataset | uspto-grants-1986_01 |
| ORD ID | ord-d92c36b19b404a7b94d49a72793acff8 |
| Source note | uspto-grants-1986_01 |