1,5-Dibromopentane → 5-(2-Allyl-4-carbomethoxyphenoxy)-1-bromopentane

HRID 1285251Notes

Reaction equation

HRID 1285251 reaction equation
[CH2:1]([C:4]1[CH:5]=[C:6]([CH:11]=[CH:12][C:13]=1[OH:14])[C:7]([O:9][CH3:10])=[O:8])[CH:2]=[CH2:3].[Br:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20]Br>>[CH2:1]([C:4]1[CH:5]=[C:6]([C:7]([O:9][CH3:10])=[O:8])[CH:11]=[CH:12][C:13]=1[O:14][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][Br:15])[CH:2]=[CH2:3]

Participants

3

Reactant 2

HCID 81001,5-DibromopentaneHCID 939882Methyl 3-allyl-4-hydroxybenzoate

Product 1

HCID 202504625-(2-Allyl-4-carbomethoxyphenoxy)-1-bromopentaneYield 69.2%

Procedure

Using the procedure of Example 1, 5.62 g (29.2 mmole) of methyl 3-allyl-4-hydroxybenzoate and 13.8 g (60 mmole) of 1,5-dibromopentane gave 6.9 g (69%) of the title compound as an oil. Calc: C, 56.32; H, 6.20; Found; C, 55.91; H, 6.20.

Sources & evidence

ORD record
ord-ed46f4e796d14cffb37858415b9d7a5f
Source dataset
uspto-grants-1986_01
Patent number
US04565882

Reaction notes

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