2-Butanamine, 3,3-dimethyl- → HCID 67830760, compound

HRID 1285369Notes

Reaction equation

HRID 1285369 reaction equation
[N+:1]([CH:4]=[C:5]([NH:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)SC)([O-:3])=[O:2].[CH3:15][CH:16]([NH2:21])[C:17]([CH3:20])([CH3:19])[CH3:18]>>[N+:1]([CH:4]=[C:5]([NH:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[NH:21][CH:16]([CH3:15])[C:17]([CH3:20])([CH3:19])[CH3:18])([O-:3])=[O:2]

Participants

3

Reactant 2

HCID 5209072-Butanamine, 3,3-dimethyl-HCID 1482249Benzenamine, N-[1-(methylthio)-2-nitroethenyl]-

Product 1

HCID 67830760HCID 67830760, compound

Conditions

Temperature
100 °C

Procedure

A mixture of 10.5 g (0.05 mol) of 2-nitro-1-anilino-1-methylthioethene and 15.2 g (0.15 mol) of 1,2,2-trimethylpropylamine was heated at 100° C. for 5 hours. After the mixture had cooled, it was concentrated on a rotary evaporator and the residue was recrystallized from ethanol.

Workup

  1. temperatureAfter the mixture had cooled
  2. concentrationit was concentrated on a rotary evaporator
  3. customthe residue was recrystallized from ethanol

Sources & evidence

ORD record
ord-d7d14885b571489093b365fad7ff5b6f
Source dataset
uspto-grants-1986_01
Patent number
US04567188

Reaction notes

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