2-Nitrobenzoyl chloride → HCID 178522658, compound

HRID 1285381Notes

Reaction equation

HRID 1285381 reaction equation
O.[NH2:2][C:3]1[NH:7][N:6]=[N:5][N:4]=1.[N+:8]([C:11]1[CH:19]=[CH:18][CH:17]=[CH:16][C:12]=1[C:13](Cl)=[O:14])([O-:10])=[O:9]>O>[N+:8]([C:11]1[CH:19]=[CH:18][CH:17]=[CH:16][C:12]=1[C:13]([NH:2][C:3]1[NH:7][N:6]=[N:5][N:4]=1)=[O:14])([O-:10])=[O:9]

Participants

4

Reactant 2

HCID 118752-Nitrobenzoyl chlorideHCID 178509300HCID 178509300, compound

Product 1

HCID 178522658HCID 178522658, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

To a solution of 10.3 g of 5-aminotetrazole monohydrate in 300 ml of tetahydrofuran and 15 ml of water was added 9.3 g of 2-nitrobenzoyl chloride. The solution was allowed to stand for 30 minutes before it was diluted with 200 ml of water and stored in a refrigerator for 72 hours. The solid which formed was separated by filtration to give 2-nitro-N-(1H-tetrazol-5-yl)benzamide melting at about 272°-273° C. with decomposition.

Workup

  1. waitstored in a refrigerator for 72 hours
  2. customThe solid which formed
  3. customwas separated by filtration

Sources & evidence

ORD record
ord-0fe5f7b51e2242e1961ab00e2fdf4761
Source dataset
uspto-grants-1986_01
Patent number
US04567193

Reaction notes

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