Acrylonitrile → 3-(Dodecylsulfanyl)propanenitrile

HRID 1287193Notes

Reaction equation

[CH2:1]([SH:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[C:14](#[N:17])[CH:15]=[CH2:16].C[O-].[Na+]>>[CH2:1]([S:13][CH2:16][CH2:15][C:14]#[N:17])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]

Participants

Reactant 3

HCID 7855Acrylonitrile

HCID 81951-Dodecanethiol

HCID 10942334Sodium Methoxide

Product 1

HCID 161025343-(Dodecylsulfanyl)propanenitrile

Procedure

β-n-Dodecylmercaptopropionitrile was prepared according to the procedure of Example 1 using 1-dodecanethiol (24.75 g; 0.12 moles), acrylonitrile (6.4 g; 0.21 moles) and sodium methoxide (0.5 g).

Sources & evidence

ORD record: ord-e39baaf36b954ae7962db26b308dd6fd
Source dataset: uspto-grants-1976_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US03984336

Reaction notes

Loading…