Acrylonitrile → 3-[(2-Methylpropyl)sulfanyl]propanenitrile

HRID 1287195Notes

Reaction equation

[CH3:1][CH:2]([CH3:5])[CH2:3][SH:4].[C:6](#[N:9])[CH:7]=[CH2:8].C[O-].[Na+]>>[CH3:1][CH:2]([CH3:5])[CH2:3][S:4][CH2:8][CH2:7][C:6]#[N:9]

Participants

Reactant 3

HCID 7855Acrylonitrile

HCID 10558Isobutyl mercaptan

HCID 10942334Sodium Methoxide

Product 1

HCID 149678433-[(2-Methylpropyl)sulfanyl]propanenitrile

Procedure

β-(2-Methyl-1-propylmercapto)propionitrile was prepared according to the procedure of Example 1 using 2-methyl-1-propanethiol (25.0 g; 0.28 moles), acrylonitrile (14.9 g; 0.28 moles) and sodium methoxide (0.5 g).

Sources & evidence

ORD record: ord-83d461717caa434b84b11fc1cb505ea8
Source dataset: uspto-grants-1976_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US03984336

Reaction notes

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