Acrylonitrile → 3-(Phenylsulfanyl)propanenitrile

HRID 1287200Notes

Reaction equation

[C:1]1([SH:7])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:8](#[N:11])[CH:9]=[CH2:10].C[O-].[Na+]>>[C:1]1([S:7][CH2:10][CH2:9][C:8]#[N:11])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

Reactant 3

HCID 7855Acrylonitrile

HCID 7969Thiophenol

HCID 10942334Sodium Methoxide

Product 1

HCID 2200313-(Phenylsulfanyl)propanenitrile

Procedure

β-Phenylmercaptopropionitrile was prepared according to the procedure of Example 1 using thiophenol (25.0 g; 0.23 moles), acrylonitrile (12.2 g; 0.23 moles) and sodium methoxide (0.5 g).

Sources & evidence

ORD record: ord-1f849f9a9ebb4f76a0a4024469fabff6
Source dataset: uspto-grants-1976_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US03984336

Reaction notes

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